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OLD BRIDGE CHEMICALS, INC.
OLD WATERWORKS ROAD
OLD BRIDGE, NJ 08857
Telephone: 732-727-2225
Facsimile: 732-727-2653
info@oldbridgechem.com
www.oldbridgechem.com
Material Safety Data Sheet
 
  June 1, 2007
 
Product Name: BASIC COPPER SULFATE
   
Manufacturer:
Old Bridge Chemicals, Inc.
P.O. Box 194
Old Bridge, New Jersey 08857
Telephone:
(732) 727-2225
Emergency Telephone:
(800) 275-3924
24-hour Emergency Telephone:
(800) 424-9300 Chemtrec
HAZARD CLASSIFICATION:
NFPA:Health-3 / Fire-0 / Reactivity-0
 
HMIS: Health-3 / Fire-0 / Reactivity-0
 
This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200).
SECTION I MATERAIL IDETIFICATION
   
Common Name:
Basic Copper Sulfate
Synonyms:
Tri-Basic Copper Sulfate, Copper Sulfate Basic, Fixed Copper
Molecular Formula:
CuSO4 . 3Cu(OH) 2 . H2O
EPA Reg. Number:
46923-2
CAS Number:
1344-73-6
SECTION II INGREDIENTS
   
Elemental Copper:
(CAS No. 7758-98-7) 53.0%
Inert:
(CAS No. N/A) 47%
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SECTION III PHYSICAL DATA
   
Physical State:
Fine light bluish-green powder.
Boiling Point:
N/A
Melting Point:
572° F (decomposes)
Specific Gravity:
0.800 – 0.900
Solubility in H2O:
Insoluble (soluble in acids)
Appearance:
Bluish-green fine powder
Odor:
Odorless
SECTION IV FIRE AND EXPLOSION DATA
   
Flash Point:
Not applicable.
Flammable Limits:
Not flammable. If heated above 570° C it can decompose to emit toxic fumes of oxide and sulfur.
Extinguishing Media:
Basic Copper Sulfate does not burn nor will it support combustion. Use dry chemical, Carbon Dioxide, foam or water mist or fog. If stored with other combustible products use water, CO2 or dry chemical.
Special Fire Fighting Instructions:
If dry heated above 300° C, SO2 is evolved. If water is used, dike fire control water for later disposal. Keep away from streams or lakes.
Fire and Explosion Hazards:
None.
   
   
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SECTION V REACTIVITY DATA
Stability:
Stable at normal temperatures.
Conditions to Avoid:
May burn, but will not ignite.
Incompatibility:
Mixing with acid will solubilize product producing water soluble products.
Hazardous Decomposition Products:
None at normal production temperatures and
pressures. If dry heated above 300° C toxic sulfur
may evolve.
Polymerization:
Will not occur.
SECTION VI HEALTH AND HAZARD INFORMATION
Swallowing: Ingestion can cause diarrhea, vomiting and stomach
pain. LD50 (male rats) = 1000 mg/Kg.
Skin : Certain individuals may be sensitive to copper
Eyes: Severe eye irritant. Causes substantial, but temporary eye damage. May be corrosive to eyes.
Eye irritation score:
(Unwashed) 24 hours = 14.33
(Unwashed) 48 hours = 13.33
(Unwashed) 72 hours = 3.33
(Unwashed) 7 days = 0
Inhalation: Inhalation of dust may cause irritation to upper respiratory tract
Carcinogenicity:
None as per NTP, OSHA, and IARC.
SECTION IV FIRST AID PROCEDURES
Ingestion:
Give large amounts of milk or water. Induce vomiting. Do not give anything by mouth or induce vomiting if the person is unconscious. Call Poison Control Center or a physician.
Skin:
Wash thoroughly with soap and water. Remove and wash contaminated clothing before reuse. Get medical attention if necessary.
Eyes:
Immediately flush eyes with plenty of water for 15 minutes. Hold eyelids apart during irrigation. Call a physician.
Inhalation:
Remove person to fresh air and call a physician. If not breathing, administer artificial respiration. Get medical attention.
Carcinogenicity:
None
SECTION VI HANDLING PRECAUTIONS
   
Personal Protective Equipment:
Chemical safety goggles. Gloves and protective clothing should be worn to prevent prolonged skin contact.
Respiratory Protection:
Wear an approved respirator for dusts or mists.
SECTION VII ENVIRONMENTAL AND DISPOSAL INFORMATION
   
Aquatic Toxicity:
Daphnia LC50 at = In excess of 320 ug/l.
Spills and Leaks:
Comply with Federal, State, and local regulations on reporting spills. Do not wash away the powder. Recover dry if possible. If product is in a confined
solution, pump into a chemical waste container.
Waste Disposal:
Do not reuse container. Dispose of powder or
solutions and container in accordance with Federal,
State, and local regulations
Environmental Effects:
Toxic to fish and plants.
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SECTION VIII. SPECIAL PRECAUTIONS
   
Storage:
Store in a dry place.
Other Precautions:
None other than those stated in the MSDS or on the package
 
SECTION IX REGULATORY INFORMATION
   
NOTICE: The information herein is presented in good faith and believed to be accurate. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ from one location to another. It is the buyer’s responsibility to ensure that its activities comply with Federal, State, and local laws.
 
SARA 313 INFORMATION: This product contains the following substance subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: COPPER COMPOUND 53.0%
SARA HAZARD CATEGORY: This product has been reviewed according to the EPA“Hazard Categories” promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following category:
AN IMMEDIATE HEALTH HAZARD
SECTION X SHIPPING INFORMATION
   
DOT Shipping Name:
Non-regulated.
 
SECTION XI
MSDS PREPARATION INFORMATION
 
Prepared By:
Joel L. Goldschmidt
Vice President
 
MSDS – Basic Copper Sulfate
Old Bridge Chemicals, Inc.
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